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华北工学院
Published:1998
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吕月仙, 方莉. THEORETICAL EXPLANATION OF THE DUALREACTION NATURE OF SEVERAL ORGANIC MOLECULES[J]. 1998, (2).
DOI:
吕月仙, 方莉. THEORETICAL EXPLANATION OF THE DUALREACTION NATURE OF SEVERAL ORGANIC MOLECULES[J]. 1998, (2). DOI:
本文在阐述普遍化微扰理论(GeneralizedPerturbationTheory)的基本方程式(简称GP方程)和两类控制反应的基础上,解释了一些亲电试剂或亲核试剂的双重反应性.作为GP方程的特例,用轨道相互作用图象解释某些有机分子的特定反应双重性:构型保持与构型转化等.
This paper explains the dualreaction nature of some electrophilic reagents and nucleophilic reagents
on the basis of elaborating generalized perturbation (GP) theory and two kinds of controlled reaction. As a special case of GP equation
by using orbital interaction pattern
the special dualreaction nature
configuration retaining and configuration inversion of some organic molecules are explained.
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