Process for the Substitution of Hexachlorocyclotriphosphazene

刘亚青; 王志军

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Process for the Substitution of Hexachlorocyclotriphosphazene

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- Process for the Substitution of Hexachlorocyclotriphosphazene
- 三聚氯化磷腈取代反应的研究
- Issue 3, Pages: 162-165(2003)
- 作者机构：
  
  1. ,山西,太原,030051
  2. 华北工学院化学工程系
  3. 华北工学院机械电子工程系,山西,太原,030051
- 作者简介：
- 基金信息：
- DOI：
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- Published：2003
- 稿件说明：
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刘亚青, 王志军. Process for the Substitution of Hexachlorocyclotriphosphazene[J]. 2003, (3): 162-165.
DOI：

刘亚青, 王志军. Process for the Substitution of Hexachlorocyclotriphosphazene[J]. 2003, (3): 162-165. DOI：

摘要

　通过三聚氯化磷腈分子中的氯原子被苯氧基、胺乙氧基取代的反应制得四苯氧基-二胺乙氧基三聚磷腈衍生物

然后再使该取代产物与甲苯二异氰酸酯反应获得功能性高分子材料.为三聚氯化磷腈转化为功能性高分子材料提供了一条新途径.

Abstract

The chlorine in the hexachlorocyclotriphosphazene molecule are substituted by phenoxy or aminoethyloxy

and tetraphenoxydiaminoethyloxycyclotriphosphazene has been obtained. This derivative then reacts with toluenediisocyanate to produce a type of functional macromolecule material. A novel process for making hexachlorocyclotriphosphazene into functional macromolecule materials is described.

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references

　AllcockHR.Developmentattheinterfaceofinorganicandpolymerchemistry[J].InorganicMacromolecules,1985,(18):22.

　张净.聚氯化磷腈衍生物的开发应用[J].化工新型材料,1990,(2):34.

　郑福安,王志强,林志宏,等.环状氯化磷腈的合成[J].吉林大学自然科学学报,1992,(2):119.

　AllcockHR.Processfortheproductionofphosphazenepolymers[P].U.S.Pat.,3370032,1986.

　贡长生.聚磷腈的合成和应用研究进展[J].现代化工,1991,(6):24.

　AllcockHR,KarynV,YoungBK.Polyphosphazeneswithunsaturatedsidegroupsusefulasreactionintermediates,crosslinkablepolymersandascomponentsofinterpenetratingpolymernetworks[P].U.S.Pat.,5,747,604,1998.

　SnyderDL,StayerML.Catalysisofphosphazenecyclicstopolymerusinglewisacidcompounds[P].U.S.Pat.,4,123,503,1978.

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