Synthetic Techniques of Tri (4-hydroxyphenyl) Methane Glycidyl Ether

张彦飞; 宁炳全

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Synthetic Techniques of Tri (4-hydroxyphenyl) Methane Glycidyl Ether

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- Synthetic Techniques of Tri (4-hydroxyphenyl) Methane Glycidyl Ether
- 三酚基甲烷三缩水甘油醚的合成工艺
- Issue 3, Pages: 212-215(2005)
- 作者机构：
  
  1. ,山西,太原,030051
  2. 中北大学化学工程系
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2005
- 稿件说明：
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张彦飞, 宁炳全. Synthetic Techniques of Tri (4-hydroxyphenyl) Methane Glycidyl Ether[J]. 2005, (3): 212-215.
DOI：

张彦飞, 宁炳全. Synthetic Techniques of Tri (4-hydroxyphenyl) Methane Glycidyl Ether[J]. 2005, (3): 212-215. DOI：

摘要

　主要研究以三酚基甲烷和环氧氯丙烷(ECH)为原材料

在催化剂作用下缩合制备三酚基甲烷三缩水甘油醚.实验结果表明:在三酚基甲烷∶ECH=1∶30

NaOH的质量分数为30%

反应温度为44℃

反应体系水含量0.3%～2%的条件下

可得到环氧值为0.57～0.59

产率为96%的三酚基甲烷的低分子环氧树脂.

Abstract

Tri (4-hydroxyphenyl) methane and epoxy chloropropane are synthesized to produce the condensed tri (4-hydroxyphenyl) methane glycidyl ether in the presence of some catalysts. The results of experiments showed that 96 percent of production of tri (4-hydroxyphenyl) methane low-molecular weight epoxy resin whose epoxide number is 0.57～0.59 can be obtained

under the following conditions: the ratio of epoxy chloropropane to tri (4-hydroxyphenyl) methane is 30; the concentration of sodium hydroxide is 30%; the reaction temperature is 44 ℃; the aqueous content is 0.3%～2%.

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