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太原师范学院化学系
Published:2009
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田芳. Determination of Aspartic and Taurine by Acetanilide-Co2+ Modified Platinum Electrode[J]. 2009, 30(6): 584-589.
在pH=5.0的三酸(H3PO4-H3BO3-HAc)盐(PBA)缓冲液中
应用方波循环伏安法
用乙酰苯胺合钴化学修饰圆盘铂电极测定天冬酸和牛黄酸的含量
并优化了实验条件.结果表明
乙酰苯胺合钴修饰圆盘铂电极用于天冬酸和牛黄酸含量的分析
在4.0×10-9
2
.0×10-6mol/L浓度范围内天冬酸峰电流与浓度呈良好的线性关系
检出限为1.0×10-9mol/L
回收率在97%左右;在2.0×10-7
2
.0×10-5mol/L浓度范围内牛磺酸峰电流与浓度呈良好的线性关系
检出限为2×10-8mol/L
回收率在95%左右.修饰电极灵敏度高
检出限底
具有良好的重现性、稳定性
为氨基酸的电化学检测提供了一个灵敏的新方法.
A platinum electrode was chemical modified with acetanilide-Co2+ by square cyclic voltammetry method(SCV) in pH=5.0 three acid(H3PO4-H3BO3-HAc) buffer solution for the determination of aspartic and taurine acid
and the experimental conditions were optimized.The results show that the modified platinum electrode has good stability and reproducibility.For aspartic and taurine acid
the linear range is 4.0×10-9
2
.0×10-6 mol/L and 2.0×10-7
2
.0×10-5 mol/L
respectively.The detection limit is 1.0×10-9 mol/L and 2.0×10-8 mol/L respectively.The recovery rate is about 97% and about 95% respectively.The method has the advantages of high sensibility and low detect limit
and can be applied to the determination of aspartic and taurine acid by SCV.
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