Reaction Network of Hydrocarbon Selective Oxidation to   Maleic Anhydride

梁日忠; 陈标华; 李成岳

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Reaction Network of Hydrocarbon Selective Oxidation to Maleic Anhydride

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- Reaction Network of Hydrocarbon Selective Oxidation to Maleic Anhydride
- 烃选择氧化制顺丁烯二酸酐的反应网络
- Issue 2, Pages: 105-111(2001)
- 作者机构：
  
  1. 北京化工大学可控化学反应教育部重实验室,北京,100029
  2. 华北工学院化学工程系!山西太原030051.北京化工大学可控化学反应教育部重实验室
  3. ,山西,太原,030051
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Published：2001
- 稿件说明：
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梁日忠, 陈标华, 李成岳. Reaction Network of Hydrocarbon Selective Oxidation to Maleic Anhydride[J]. 2001, (2): 105-111.
DOI：

梁日忠, 陈标华, 李成岳. Reaction Network of Hydrocarbon Selective Oxidation to Maleic Anhydride[J]. 2001, (2): 105-111. DOI：

摘要

目的　综述烃类选择氧化制顺丁烯二酸酐反应网络的研究进展 .方法　检索分析国内外相关资料 .结果　重点介绍烃类晶格氧选择氧化的原理、工艺

并对烃类选择氧化制顺丁烯二酸酐的反应网络进行讨论 .结论　提出了烃类选择氧化制顺丁烯二酸酐今后研究的重点和方向

Abstract

Aim\ To summarize reaction networks of hydrocarbon selective oxidation to maleic anhydride using lattice oxygen of catalyst as oxidant. Methods\ The interrelated data home and abroad were searched and analyzed. Results\ The principles and technologies of hydrocarbon selective oxidation are introduced emphatically. Reaction networks of maleic anhydride are discussed. Conclusion\ Some objectives in this field are brought forward.

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[1 ]　黄仲涛 ,曾昭槐 .石油化工过程催化作用 [M].北京 :中国石化出版社 ,1 995.

[2 ]　 Grasselli R K,Burrington JD.Characterization of the reactions in vanadium phosphate catalystmicrostructure withpreparation route[J].Adv Cata,1 981 ,3 0 ,1 3 3 .

[3 ]　 Moro-Oka Y,Ueda W.Reactivity and structure of vansdyl pyrophosphate as a butane oxidation catalyst[J].AdvCatal,1 994 ,4 0 :2 3 3 .

[4 ]　 Mars P,Van Krevenlen D W.Oxidation carried outby means of vanadium oxide catalysts[J].Chem Eng Sc,1 954,(Special Suppl) 3 :4 1 .

　 Harber J.Mechanochemistry:the activation method of vpo catalystsfor n-butane partial oxidation[J].Stud Surf SciCatal,1 992 ,72 :2 79.

　 Fujimoto K.Fundamental study of the oxidation of butane over vanadyl pyrosphate[J].Stud Surf Sci Catal 1 994 ,81 :73 .

　 Haggin J.Innovations in catalysis create environmentally friendly THF process[J].C&EN,1 995,73 (Apr.3 ) :2 1 .

　黄晓峰 .丁烷选择氧化制顺丁烯二酸酐动态动力学模型及其应用 [D].北京 :北京化工大学 ,1 999.

　 Schwendeman M N,Mc Brige R,Reuter D,Isaacs M.Porous metal filters preventfluid bed catalystloss[J].ChemProcess,1 983 :1 0 0 .

[1 0 ]　 Emig G,Martin F.Separation of catalystoxidation and reduction-an alternative to the conventional oxidation of n-butane to maleic anhydride[J].Catal Today,1 987,1 :4 77.

[1 1 ]　 Contractor R M,Bergna H E,Horowitz H S,et al.,Butane oxidation in a transport bed reactor -redoxcharacteristic of the vanadium phosphorus oxide catalyst[J].Catal Today,1 987,1 :4 9.

[1 2 ]　Contractor R M,Sleight A W.Dupont’s CFB technology for maleic anhydride[J].Catal Today,1 988,3 :1 75.

[1 3 ]　 Contractor R M,Garnett B I,Horowitz H S,et al. A new commercial scale process for n-butane oxidation tomaleic anhydride using a circulating fluidized bed reactor[M].New developmentin selective oxidation .CorberanV C &Bellon S V,Eds,Elsevierscience.B V Amsterdam 1 994 ,2 3 3 .

[1 4 ]　Emig G,Uihlein K,Hacker C J.Selective synthesis of maleicanhydride by spatial separation of n-butane oxidatioand catalystreoxidation[J].Stud Surf Sci Catal,1 994 ,82 :2 4 3 .

[1 5]　 Keller G E,Bhasin M M.Synthesis of ethylene via oxidation coupling of methane :Determination of activecatalyst[J].JCatal,1 982 ,73 :9.

[1 6]　 Centi G,Trifiro F,Ebner JR,etal.Mechanistic aspects of maleic anhydride synthesis from C4 hydrocarbons overphosphorus vanadium oxide[J].Chem Rev,1 988,88:55～ 80 .

[1 7]　Centi G,Fornasari G,Trifiro F.On the mechanism of n-butane oxidation to maleicanhydride:oxidation in oxygen-stoichiometry-controlled conditions[J].JCatal,1 984 ,89:4 4～ 51 .

[1 8]　 Cavani F,Trifiro F.Catalyzing butane oxidation to make maleic anhydride[J].Chemtech,1 994 ,1 8(4 ) :1 8～ 2 5.

[1 9]　Escardino A,Sola C,Ruiz F.Maleic anhydride by catalytic oxidation of butane- :mechanism of the reaction, kinetic study (atpartial hydrocarbon feed pressure below 7.5mm mercury) [J].An Quim,1 973 ,69:3 85～ 3 96,1 1 57～ 1 1 68.

[2 0 ]　 Varma R L,Saraf D W.Oxidation of butene to maleicanhydride :kinetic and mechanism[J].JCatal,1 978,55:3 61 .

[2 1 ]　Trimm D L.Design of Industrial Catalysts[M].Elsevier:New York,1 980 .

[2 2 ]　 Gleaves JT,Ebner JR,Kuechler T C.Temporal analysis of products -a unique catalyst evaluation system withsubmillisecond time resolution[J].Cata Rev,1 988,3 0 (1 ) :4 9～ 1 1 6.

[2 3 ]　Schuurman Y,Gleaves JT.Activation of vanadium phosphorus oxide catalysts for alkane oxidation:the influenceof the oxidation state on catalystselectivity[J].Ind Eng Chem Res,1 994 ,3 3 :2 93 5～ 2 94 1 .

[2 4 ]　Schuurman Y,Gleaves JT.A comparison of steady-state and unsteady-state reaction kinetics of n-butane oxidationover VPO catalysts using a TAP-2 reactor system[J].Catal,Today,1 997,3 3 (Nos1～ 3 ) :2 5～ 3 7.

[2 5]　 Xue Z Y,Schrader G L.Transient FTIR studies of the reaction pathway for n-butane selective oxidation overvanadyl oyrophosphate[J].JCatalysis,1 999,1 84 :87～ 1 0 4 .

[2 6]　 Centi G.Vanadyl pyosphosorus -a critical overview[J].Catal Today,1 993 ,1 6(1 ) :5～ 2 6.

[2 7]　 Buchanan JS,Sundaresan S.Kinetics and Redox properties of vanadium phosphate catalysts for butane oxidation[J].Appl Catal,1 986,2 6:2 1 1～ 2 2 6

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