曹雄, 徐莹, 程松, et al. 硝酸磷钾肥水溶液热安全性研究[J]. 2009, (3).DOI:
硝酸磷钾肥水溶液热安全性研究
摘要
为了防止化肥生产过程发生爆炸事故
利用自制实验装置对硝酸磷钾肥水溶液的热安全性进行了实验研究.结果表明
硝酸铵的浓度对硝酸磷钾复合肥水溶液临界爆炸温度的影响很大
硝酸铵浓度越高
其临界爆炸温度就越低
也越易爆炸;单纯的氯离子有抑制硝酸磷钾水溶液爆炸的作用;硝酸及氯离子两者同时存在时
可使硝酸磷钾水溶液的分解反应加速进行
降低其临界爆炸温度.研究结果对相关化肥企业的安全生产有指导意义.
Abstract
To prevent the explosive accident in the process of fertilizer production
thermal safety of phosphorus-potassium nitrate fertilizer in aqueous solution was studied by using the self-designed devices.The results show that the concentration of ammonium nitrate has a great effect on critical explosion temperature of the phosphorus-potassium nitrate aqueous solution.The higher the concentration of ammonium nitrate is
the lower the critical explosion temperature becomes
the more easily the ammonium nitrate explodes.The chloride ion alone existed inhibits the explosion of phosphorus-potassium nitrate fertilizer in aqueous solution.Nitrate acid and chloride ions existed at the same time accelerate its decomposition reaction and reduce the critical explosion temperature.The results have important guiding significance on the production safety of fertilizer-related enterprises.