溶剂对四氯合铜乙二胺结构和性能的影响

张京; 高艳阳

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溶剂对四氯合铜乙二胺结构和性能的影响

更新时间：2026-09-14

- 溶剂对四氯合铜乙二胺结构和性能的影响
- 溶剂对四氯合铜乙二胺结构和性能的影响
- Issue 1, (2013)
- 作者机构：
  
  中北大学理学院
- 作者简介：
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- DOI：
  CLC：
- Published：2013
- 稿件说明：
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张京, 高艳阳. 溶剂对四氯合铜乙二胺结构和性能的影响[J]. 2013, (1).
DOI：

张京, 高艳阳. 溶剂对四氯合铜乙二胺结构和性能的影响[J]. 2013, (1). DOI：

摘要

分别以水和乙醇/水为溶剂

采用液相合成方法制备了有机-无机杂合物四氯合铜酸乙二铵([H3N(CH2)2NH3]CuCl4)

通过X射线衍射(XRD)和差示扫描量热(DSC)等测试手段对其结构和性能进行了表征.结果表明

不同溶剂对产物[H3N(CH2)2NH3]CuCl4的晶体结构和固-固相变性能有明显的影响.在乙醇/水介质中

晶体具有较高的a轴择优生长取向

所得产物层状结构明显

具有较高的固-固相变焓.

Abstract

Organic-inorganic hybrid compound ethylenediamine tetrachlorocuprate([H3N(CH2)2NH3]CuCl4) were prepared by liquid phase technology respectively with water and ethanol/water as solvent.Their structure and performance were characterized by X-ray diffraction(XRD) and differential scanning calorimetry(DSC).The results indicate that different solvent has significant influence on the crystal structure and property of solid-solid phase transition of the product [H3N(CH2)2NH3]CuCl4.In ethanol/water medium

the crystal show a preferred orientation along a-axis

and the product prepared in ethanol/water medium show significant layered structure and a higher solid-solid phase transition enthalpy values.

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