添加剂对PVC结晶影响的傅立叶转换红外光谱研究

刘亚群; 张超灿

您当前的位置：

首页 >

文章列表页 >

添加剂对PVC结晶影响的傅立叶转换红外光谱研究

更新时间：2026-09-14

- 添加剂对PVC结晶影响的傅立叶转换红外光谱研究
- Fourier-Transform Infrared Spectrum Study on the Influence of Additives on Polyvinyl-Chloride Crystallization
- 中北大学学报（自然科学版） 2006年第1期页码：49-54
- 作者机构：
  
  1. 武汉理工大学理学院应化系
  2. 武汉理工大学材料学院
- 作者简介：
- 基金信息：
  
  湖北省科技攻关计划重大项目(2002AA105A01)
- DOI：
  中图分类号：
- 纸质出版：2006
- 稿件说明：
移动端阅览
刘亚群, 张超灿. 添加剂对PVC结晶影响的傅立叶转换红外光谱研究[J]. 中北大学学报（自然科学版）, 2006,(1):49-54.

刘亚群, 张超灿. Fourier-Transform Infrared Spectrum Study on the Influence of Additives on Polyvinyl-Chloride Crystallization[J]. 2006, (1): 49-54.
刘亚群, 张超灿. 添加剂对PVC结晶影响的傅立叶转换红外光谱研究[J]. 中北大学学报（自然科学版）, 2006,(1):49-54. DOI：

刘亚群, 张超灿. Fourier-Transform Infrared Spectrum Study on the Influence of Additives on Polyvinyl-Chloride Crystallization[J]. 2006, (1): 49-54. DOI：

摘要

以乙酰苯胺、己二酸和邻苯二甲酸氢钾作为添加剂

利用傅立叶转换红外光谱研究了三种添加剂对PVC分子构象的影响.通过对结晶特征吸收峰的分析

表明结晶相中PVC分子链均为反式间规的伸展链构象.乙酰苯胺和己二酸使PVC的结晶度增大

而邻苯二甲酸氢钾则使PVC结晶度减小.对无定型相PVC分子构象的研究结果表明

乙酰苯胺和己二酸使无定型相中的短反式有序构象增加

同时使TTG*G*构象缺陷增多.因此乙酰苯胺和己二酸可以使PVC的折叠链晶体结构含量增大

使结晶变得完善.此外

己二酸既改变了无定型相PVC分子链构象

也使结晶相PVC分子链构象改变

而乙酰苯胺和邻苯二甲酸氢钾只影响非晶PVC分子链构象.

Abstract

Acetanilide

adipic acid and potassium hydrogen phthalate are chosed as additives for PVC

and their effects on PVC molecule conformation are studied by FT-IR.From the analysis of the crystalline absorption

it is infered that in crystalline phase

PVC chains are in extended chain conformation. In addition

acetanilide and adipic acid increase the proportion of PVC crystalline phase

while potassium hydrogen phthalate decreases PVC crystallinity.For amorphous PVC

acetanilide and adipic acid enhance the shorttrans-syndiotactic sequence absorption

and make the part of TTG*G* conformation defect increase.Thus

acetanilide and adipic acid raise the percentage of chain-folded crystal and perfect PVC crystallinity.In addition

acetanilide and potassium hydrogen phthalate can only interact with amorphous PVC chains

however

adipic acid not only influences amorphous PVC chain conformation

but also can affect PVC crystalline phase.

关键词

Keywords

references

D AW SON P C,G ILBERTM.COM PARIS ION OF X-RAY D IFFRACTION AND THERM A L ANA LYS IS M ETHODS FOR ASSESS ING ORDER IN PO LY(V INY L CH LORIDE)[J].J.PO LYM.SC I.:PART B:PO LYM.PHYS.ED I.,1991,29:1407.

HUANG ZH IM ING,B AO Y ONGZHONG.E FFECTS OF M ICRO-CRYSTA LLITE CROSSLINK ING NETW ORKS ON THE PROPERTIES OF P LASTIC IZEDPO LY(V INY L CH LORIDE)[J].PO LYM ERM ATERIA LS SC IENCE AND ENG INEERING,1999,15(3):109.

G ARBARCZYK J,PAUKSZTA D.IN FLUENCE OF ADD ITIVES ON THE STRUCTURE AND PROPERTIES OF PO LYM ERS 3.STUDY OF TRANS ITION INISOTACTIC PO LYPROPY LENE AT VARIOUS TEM PERATURES AND TIM ES OF HEATING[J].CO LLO ID&PO LYM ER SC IENCE,1985,263:985.

G IU LIO T RU TURRO,B ROW N G R.E FFECT OF S ILICA NUCLEAN TS ON THE RATES OF CRYSTA LLIZATION OF PO LY(ETHY LENE TEREPH THA LATE)[J].PO LYM ER,1984,25:659.

L EGRA R,B A ILLY C.CHEM ICA L NUCLEATION,A NEW CONCEPT AP LLIED TO THE M ECHAN ISM OF ACTION OF ORGAN IC AC ID SA LTS ON THECRYSTA LLIZATION OF PO LYETHY LENE TEREPH THA LATE AND B ISPHENO L-A PO LYCARBONATE[J].PO LYM ER,1984,25:835.

Q IAOW ENQ IANG,F AN X IAODONG.E FFECT OF P-HYDROXYBENZO IC AC ID ON CRYSTA LLIZATION BEHAV IOR AND M ECHAN ICA L PROPERTIESOFHDPE[J].CH INA P LASTICS,2003,17(4):27.

L IU Y AQUN,ZHANG CHAOCAN.T HE IN FLUENCE OF ADD ITIVES ON PO LYV INY L CH LORIDE CRYSTA LLIZATION[J].JOURNA L OF W UHANU N IVERS ITY OF T ECHNO LOGY—M ATERIA LS SC IENCE.SUBM ITTED.

M ATSUBA G,K A JIK,N ISH IDAK.CON FORM ATIONA L CHANGE AND ORIEN TATION FLUCTUATIONS PRIOR TO THE CRYSTA LLIZATION OFSYND IOTACTIC PO LYSTYRENE[J].M ACROM O LECU LES,1999,32:8932.

毕大芝,张斌.聚合物共混物的红外光谱研究[J].中国塑料,2002,16(7):83.B ID AZH I,ZHANG B IN.S TUDY OF PO LYM ER B LENDS BY IN FRARED SPECTRUM[J].CH INA P LASTICS,2002,16(7):83.(INCH INESE).

张美珍,王桂花.用红外光谱法研究聚氯乙烯的增塑机理[J].北京化工大学学报,2000,27(2):30.ZHANG M E IZHEN,W ANG G U IHUA.S TUDY OF THE M ECHN ISM IN P LASTIC IZED PVC W ITH IN FRARED SPECTROGRAPHY[J].JOURNA LOF B E IJING U N IVERS ITYOF CHEM ICA L T ECHNO LOGY,2000,27(2):30.(IN CH INESE).

何其佳,张爱民.聚氯乙烯微晶结构原位红外光谱的研究[J].高分子材料科学与工程,2003,19(4):220.H E Q IJIA,ZHANG A IM IN.S TUDY ON THE M ICROCRYSTA LLINE STRUCTURE OF PVC BY IN-S ITUFT-IR[J].PO LYM ER M ATERIA LSSC IENCE AND ENG INEERING,2003,19(4):220.(IN CH INESE).

K RIMM S,ENOM OTO S.IN FRARED STUD IES OF CON FORM ATIONA L CHANGES IN PO LYV INY L CH LORIDE[J].JOURNA L OF PO LYM ERSC IENCE:PART A,1964,2:669.

T HEODOROU M,JASSE B.FOURIER-TRANSFORM IN FRARED STUDY OF CON FORM ATIONA L CHANGES IN P LASTIC IZED PO LY(V INY LCH LORIDE)[J].JOURNA L OF PO LYM ER SC IENCE:PO LYM ER PHYS ICS ED ITION,1983,21:2263.

T ABB D L,K OEN IG J L.FOURIER TRANSFORM IN FRARED STUDY OF P LASTIC IZED AND UNP LASTIC IZED PO LY(V INY L CH LORIDE)[J].M ACROM O LECU LES,1975,8(6):929.

K OEN IG J L,A N TOON M K.T HERM A LLY INDUCED CON FORM ATIONA L CHANGES IN PO LY(V INY L CH LORIDE)[J].J.PO LYM.S IC.:PO LYM.PHYS.ED I.,1977,15:1379.

K ITAM ARU R,HORII F.P ROTON M AGNETIC RESONANCE STUD IES OF THE PHASE STRUCTURE OF BU LK-CRYSTA LLIZED LINEARPO LYETHY LENE[J].J.PO LYM.S IC.:PO LYM.PHYS.ED I.,1977,15:821.

F LORY P J,Y OON D Y.T HE IN TERPHASE IN LAM E LLAR SEM ICRYSTA LLINE PO LYM ERS[J].M ACROM O LECU LES,1984,17:862.

G LOTIN M,M ANDE LKERN L.A R AM AN SPECTROSCOP IC STUDY OF THE M ORPHO LOG ICA L STRUCTURE OF THE PO LYETHY LENES[J].CO LLO ID&PO LYM ER SC IENCE,1982,260:182.

H AGEM ANN H,S TRAUSS H L.S TRUCTURE AND C RYSTA LLIZATION OF N-C21H44,N-C36H74,AND LOW M O LECU LAR W E IGH TPO LYETHY LENE G LASSES[J].M ACROM O LECU LES,1987,20:2810.

L EM STRA J,K E LLER A.G E LATION CRYSTA LLIZATION OF PO LY(V INY L CH LORIDE)[J].J.PO LYM.SC I.:PO LYM.PHYS.ED I.,1978,16:1507.

浏览量

296

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

邻苯二甲酸氢钾对聚氯乙烯结构和性能的影响

1-甲基-4,5-二硝基咪唑的晶体结构与热分解特性

Nd_2Fe14B晶体结构分析——在X射线定量相分析中的应用

PVC/EVA 共混物韧性的研究

Li掺杂α-Bi_2O_3电子结构和光电性质的第一性原理研究