尼龙6/11共聚物的非等温结晶动力学研究

杨坡; 胡国胜; 王标兵

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尼龙6/11共聚物的非等温结晶动力学研究

化工与环境工程 | 更新时间：2026-09-14

- 尼龙6/11共聚物的非等温结晶动力学研究
- Investigation on Nonisothermal Crystallization Kinetics of Nylon 6/11 Copolymer
- 中北大学学报（自然科学版） 2008年第2期页码：156-159
- 作者机构：
  
  中北大学高分子与生物工程研究所
- 作者简介：
- 基金信息：
  
  山西省科技攻关资助项目(052032);山西省青年科技研究基金资助项目(2006021011)
- DOI：
  中图分类号：
- 纸质出版：2008
- 稿件说明：
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杨坡, 胡国胜, 王标兵. 尼龙6/11共聚物的非等温结晶动力学研究[J]. 中北大学学报（自然科学版）, 2008,(2):156-159.

杨坡, 胡国胜, 王标兵. Investigation on Nonisothermal Crystallization Kinetics of Nylon 6/11 Copolymer[J]. 2008, (2): 156-159.
杨坡, 胡国胜, 王标兵. 尼龙6/11共聚物的非等温结晶动力学研究[J]. 中北大学学报（自然科学版）, 2008,(2):156-159. DOI：

杨坡, 胡国胜, 王标兵. Investigation on Nonisothermal Crystallization Kinetics of Nylon 6/11 Copolymer[J]. 2008, (2): 156-159. DOI：

摘要

以尼龙11预聚物和尼龙6预聚物为原料

采用熔融聚合的方法制备了尼龙6/11共聚物.利用差示量热扫描热分析仪(Differential Scanning Calorimetry

DSC)研究了尼龙6/11共聚物的非等温结晶过程

用经Jeziorny修正的Avrami方程对其非等温结晶动力学进行了研究

计算并得到非等温结晶动力学参数.结果表明:该方程适合于处理尼龙6/11共聚物的非等温结晶过程.在尼龙6/11共聚物非等温结晶过程中

在其初期结晶阶段可能同时包含了均相成核和异相成核

在二次结晶阶段结晶生长可能是一维生长;此外

还利用Kissinger方法求得尼龙6/11共聚物非等温结晶的结晶活化能为-201.76 kJ/mol.

Abstract

Nylon 6/11 copolymer was prepared by melting polycondensation polymerization of pre-polyamide 11 and pre-polyamide 6.The nonisothermal crystallization behaviors of nylon 6/11 copolymer were investigated by differential scanning calorimetry(DSC).And its nonisothermal crystallization kinetics was studied by the Avrami equations modified by Jeziorny

and some important parameters were calculated.The results show that the above equation can describe the nonisothermal crystallization of nylon 6/11 copolymer well.At primary crystallization stage

there are heterogeneous and homogeneous nucleations during crystallization.In the secondary crystallization stage

the growth is one-dimensional mode.Additionally

the activation energy of nonisothermal crystallization for nylon 6/11 copolymer obtained from Kissinger method is-201.76 kJ/mol.

关键词

Keywords

references

Hu G,Wang B,Gao F.Investigation on the rheological behavior of nylon 6/11[J].Materials Science&EngineeringA.,2006,426:263-265.

Wang B.Preparation and characterization of nylon 6/11 copolymer[J].Materials Letters,2006,60:2715-2717.

Li Y,Zhang G,Zhu X,et al.Isothermal and nonisothermal crystallization kinetics of partially melting nylon 1012[J].J.Appl.Polym.Sci.,2003,88:1311-1319.

Zhang G,Yan D J.Crystallization kinetics and melting behavior of nylon 10,10 in nylon 10,10-montmorillonitenanocomposites[J].Appl.Poly.Sci.,2003,88:2181-2188.

Zhang X,Xie T,Yang G.Isothermal crystallization and melting behaviors of nylon 11/nylon 66 alloys by in situpolymerization[J].Polymer,2006,47:2116-2126.

Cui X,Yan D,Wang Y.Isothermal and nonthermal crystallization kinetics of even-odd nylon 10 11[J].J.Appl.Polym.Sci,2005,97:1637-1643.

Liu X,Wu Q.Non-isothermal crystallization behaviors of polyamide 6/clay nanocomposites[J].Euro.Polym.J.,2002,38:1383-1389.

Jeziorny.Parameters characterizing the kinetics of the non-isothermal crystallization of poly(ethylene terphthalate)determined by DSC[J].Polymer,1978,19:1142-1144.

Kissinger H.Variation of peak temperature with heating rate in differential thermal analysis[J].J Res Bur Stds,1956,57:217-218.

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