煤矸石基聚合氯化铝铁微波水解聚合过程模型

连明磊; 胡江良; 孔德顺; 冯权莉; 艾德春

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煤矸石基聚合氯化铝铁微波水解聚合过程模型

化工与环境工程 | 更新时间：2026-09-14

- 煤矸石基聚合氯化铝铁微波水解聚合过程模型
- The Hydrolytic Polymerization Model of the Gangue-Basic PAFC by Microwave Irradiation
- 中北大学学报（自然科学版） 2012年33卷第6期页码：716-720
- 作者机构：
  
  1. 六盘水师范学院环境与化学工程系
  2. 昆明理工大学化学工程学院
- 作者简介：
- 基金信息：
  
  六盘水市科技计划资助项目(52020-2011-05);贵州省煤炭资源清洁高效利用科研实验平台资助项目(黔科平台[2011]4003);贵州省教育厅特色重点实验室资助项目(2011:278)
- DOI：
  中图分类号：
- 纸质出版：2012
- 稿件说明：
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连明磊, 胡江良, 孔德顺, 等. 煤矸石基聚合氯化铝铁微波水解聚合过程模型[J]. 中北大学学报（自然科学版）, 2012,33(6):716-720.

连明磊, 胡江良, 孔德顺, et al. The Hydrolytic Polymerization Model of the Gangue-Basic PAFC by Microwave Irradiation[J]. 2012, 33(6): 716-720.
连明磊, 胡江良, 孔德顺, 等. 煤矸石基聚合氯化铝铁微波水解聚合过程模型[J]. 中北大学学报（自然科学版）, 2012,33(6):716-720. DOI：

连明磊, 胡江良, 孔德顺, et al. The Hydrolytic Polymerization Model of the Gangue-Basic PAFC by Microwave Irradiation[J]. 2012, 33(6): 716-720. DOI：

摘要

设计了煤矸石微波法制聚合氯化铝铁的工艺流程.考虑了微波效率及体系向环境的热传导

通过相关试验

计算得到了煤矸石基聚合氯化铝铁在微波场中的水解聚合能E=257.05kJ·mol-1.引入了Ea=E的假设

建立了煤矸石基聚合氯化铝铁微波水解聚合的反应动力学方程.研究表明:320W微波功率下

反应动力学拟合方程的反应级数β=0.140

表观频率因子k0=1.10×10\+-3mol0.860·L-0.860·s-1

模型计算值与试验值拟合良好

相关系数R=0.999 9.在528W及680W两功率水平下过程模型的计算值也均与试验值拟合良好

Abstract

The flow charts for hydrolytic polymerization of the gangue-basic PAFC by microwave irradiation were designed.The microwave efficiency and heat conduction were considered

and the hydrolytic polymerization energy of the gangue-basic PAFC by microwave irradiation is identified as E=257.05 kJ·mol-1 through the related tests.Assuming Ea is equal to E

the kinetics was established.The reaction order is identified as β=0.140

and the apparent frequency factor is identified as k0=1.10×10-3 mol0.860·L-0.860·s-1 when the microwave power is 320 W.Also

the kinetic model fits well with the experimental values

and the correlation coefficient is 0.999 9.The similar situations occur in other powers

and the correlation coefficients are higher than 0.999 8 when the microwave power is 528 W or 680 W.

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Keywords

references

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