胶束催化及其在有机合成中的应用

刘启发; 于亚明; 高保娇

您当前的位置：

首页 >

文章列表页 >

胶束催化及其在有机合成中的应用

更新时间：2026-09-14

- 胶束催化及其在有机合成中的应用
- Micellar Catalysis and its Applications in Organic Synthesis
- 中北大学学报（自然科学版） 2006年第5期页码：442-447
- 作者机构：
  
  中北大学化工与环境学院
- 作者简介：
- 基金信息：
  
  山西省自然科学基金资助项目(20040402)
- DOI：
  中图分类号：
- 纸质出版：2006
- 稿件说明：
移动端阅览
刘启发, 于亚明, 高保娇. 胶束催化及其在有机合成中的应用[J]. 中北大学学报（自然科学版）, 2006,(5):442-447.

刘启发, 于亚明, 高保娇. Micellar Catalysis and its Applications in Organic Synthesis[J]. 2006, (5): 442-447.
刘启发, 于亚明, 高保娇. 胶束催化及其在有机合成中的应用[J]. 中北大学学报（自然科学版）, 2006,(5):442-447. DOI：

刘启发, 于亚明, 高保娇. Micellar Catalysis and its Applications in Organic Synthesis[J]. 2006, (5): 442-447. DOI：

摘要

概述了胶束催化作用的基本原理以及胶束催化在有机合成中的多方面应用.分析了各种因素对胶束催化的影响规律

并结合作者利用胶束催化对线型高聚物实施大分子反应的研究实践.提出了胶束催化在有机合成中将具有广阔的应用前景

可将大量的油/水两相有机反应体系高效地推向工业化生产.

Abstract

This paper summarized the principle of micellar catalysis

reviewed its various applications in organic synthesis

and described the effects of different factors on the micellar catalysis.Combining with author′s present investigation catalysis system

it is indicated that micellar catalysis has wide application foreground in organic synthesis

and a number of organic reactant systems between phase oil and water phase can been introduced into industrialization production through micellar catalysis with high efficiency and environmental protection.

关键词

Keywords

references

F end ler J H,F end ler E J.C ata lys is in M ice llar and M acrom o lecu lar System[M].A cadem ic P ress.,N ew Y ork,1975.

C ra lze lM,K a lyanasundaram K.K inetics and C ata lys is in M icrohetereneous System s[M].M arce l D ekker Inc,N ewY ork,1991:64.

T adros T h F.Som e A pp lications of Surfactan ts in B io log ica l System,in Surfactan t[M].A cdem ic P ress,London,1984.

Perez-B end ito D,R ub io S.M ice llar cata lys is in reaction-rate[J].T rends in A na l.Chem.,1993,12(1):9-18.

蔡汝秀,黄厚评.胶束介质在动力学分析中的应用[J].分析化学,1997(4):476-481.C a i R ux iu,Huang Houp ing.A pp lication of m ice llar m ed ium in k inetic ana lys is[J].Ch inese Journa l of A na lytica lChem istry,1997(4):476-481.(in Ch inese).

牟莉娟,蒋文伟.1,3-苯并二茂的微胶束催化氯甲基化新技术[J].应用化学,2000,17(5):563-565.M ou L ijuan,Jiang W enw e i.Ch lorom ethy lation of 1,3-benzod ioxo le in the presence of m ice llar cata lysts[J].Ch ineseJourna l of A pp lied Chem istry,2000,17(5):563-565.(in Ch inese).

M ukerjee P,C ard ina l J R,D esa i N R.In M ice llization,So lub ilization,and M icroem u ls ion[M].P lenum,N ewY ork,1977,1:241.

F rancesca D R,A n tone lla B,P ietro D P,et a l.Hydro lys is of 2,4-d in itropheny l phosphate in norm a l and reverse m i-ce lles[J].Chem.Soc.Perk in T rans,1995,2:673-678.

赵振国,马季铭.胶束催化假相理论模型[J].化学通报,2000(12):18-25.Zhao Zhenguo,M a Jim ing.P seudophase m ode ls of m ice llar cata lys is[J].Chm em ica l O n line,2000(12):18-25.(inCh inese).

方小牛.阴离子表面活性剂在有机合成中催化作用[J].化学研究,1999,10(2):29-34.F ang X iaon iu.T he cata lytic app lication of an ion ic surfactan ts in organ ic syn thes is[J].Chem ica l R esearches,1999,10(2):29-34.(in Ch inese).

秦合法.阴离子相转移催化的F riede l-C rafts烷基化反应[J].化学试剂,1992(3):309-312Q in H efa.F riede l-crafts a lky lation reaction cata lyzed by an ion ic phase transfer reagen t[J].Chem ica lR eagen t,1992(3):309-312.(in Ch inese).

余孝其,蓝仲薇.胶束介质中的α-氨基酸合成[J].化学研究与应用,1994,6(1):72-75.Y u X iaoq i,L an Zhongw e i.Syn thes is of-αam ino ac id in m ice llar m ed ia[J].Chem ica l R esearch and A pp lication,1994,6(1):72-75.(in Ch inese).

Schom acker R,R ob inson B H,F letcher P D I.In teration of enzym es w ith surfactan ts in adueous so lu tion and inw ater-o il[J].Chem.Soc.F araday T rans,1988,1(84):4203-4206.

于澍,李云平.胶束催化氧化合成对硝基苯甲酸[J].石油化工,2000(9):658-660.Y u Shu,L i Y unp ing.M ice lles cata lytic ox idation for the syn thes is of p-n itrobenzo ic ac id[J].Petrochem ica l T ech-no logy,2000(9):658-660.(in Ch inese).

张腾云,钟理.胶束催化合成环氧丙烷的清洁生产技术[J].现代化工,2004(2):56-58.Zhang T engyun,Zhong L i.N ew clean techno logy by m ice llar cata lys is for syn thes is of propy lene ox ide[J].M odernChem ica l Industry,2004(2):56-58.(in Ch inese).

V an den B roeke L J P,D e B ru ijn V G,H e ijinen JH M,et a l.T he ox idation techno logy w ithm ice llar cata lys is for e-pox idationof propy lene[J].In t Eng Chem R es,2001,40(23):5240-5245.

G o ldberg S I,B aba N,G reen R L.M ice lle-enzym e ana logy:stereochem ica l and substrate se lectiv ity[J].Am.Chem.Soc,1978,100(21):676-679.

张永敏.手性胶束中的有机合成[J].合成化学,1994,2(1):68-72.Zhang Y ongm in.O rgan ic reaction in ch ira lm ice lles[J].H echengE Huaxue,1994,2(1):68-72.(in Ch inese).

张永敏.物理有机化学[M].上海:上海科学技术出版社,2001.

何玉萼,张菊仙.胶束催化2,4-二硝基氯苯碱水解反应动力学研究[J].化学研究与应用,2000,12(2):234-236.H e Y ue,Zhang Jux ian.S tud ies on the k inetics of 2,4-d in itroch lorobenzene hydro lys is reaction by a lka li[J].Chem i-ca l R esearch and A pp lication,2000,12(2):234-236.(in Ch inese).

沈吉静,赵振国.阳离子表面活性剂溴代十六烷基吡啶胶束对2,4-二硝基氯苯碱水解反应的影响[J].高等学校化学学报,1997,18(9):1527-1529.Shen Jijing,Zhao Zhenguo.E ffects of cation ic surfactan t cety lpyrid ine brom ide m ice lle upon the hydro lys is of 2,4-d in itrochorobenzene[J].Chem ica l Journa l of Ch inese U n ivers ities,1997,18(9):1527-1529.(in Ch inese).

Bun ton C A,D e Buzzaccarin I F,H am ed F H.D ephosphory lation in cation ic m ice lles andM icroem u ls ions,effect ofadded a lcoho ls[J].O rg.Chem.,1983,48:2457-2459.

N ozak i K,Y osh ida M,T akaya H.R eaction rate enhancem en t by add ition of an ion ic surfactan t SDS in the ru then i-um cata lyzed hydrogen transfer from a 1,4-d io l to 4-pheny l-3-bu ten-2one[J].Journa l of O rganom eta llic Chem istry,1994,473(1-2):253-256.

蒋海珍,任仲皎.表面活性剂对肉桂酸和巴比妥酸缩合反应的影响[J].化学世界,2002(3):155-156.Jiang H a izhen,R en Zhong jiao,Pe iW e izhong.E ffect of surfactan ts upon condensation reaction of c inna ldehyde w ithbarb ituric ac id[J].Chem ica lW orld,2002(3):155-156.(in Ch inese).

孙锦宜,林西平.环保催化材料与应用[M].北京:科学技术文献出版社,2002.

浏览量

668

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

鱼类自主游动时摆频与摆幅的最优组合研究

面向量子信息的单光子探测的机制、器件及电路设计研究进展

面向高空爆炸试验的冲击波测试系统

《中北大学学报(自然科学版》》征稿简则

基于低分子质量PEI的类PEG聚合物基因载体