用于纳米微反应器的微乳液的相行为研究

王金英; 张景林; 彭英健

您当前的位置：

首页 >

文章列表页 >

用于纳米微反应器的微乳液的相行为研究

化工与环境工程 | 更新时间：2026-09-14

- 用于纳米微反应器的微乳液的相行为研究
- Study on the Phase Behavior of Microemulsion System as a Nano-Reactor
- 中北大学学报（自然科学版） 2009年30卷第4期页码：349-353
- 作者机构：
  
  1. 北京理工大学爆炸科学与技术国家重点实验室
  2. 中北大学化工与环境学院
- 作者简介：
- 基金信息：
- DOI：
  中图分类号：
- 纸质出版：2009
- 稿件说明：
移动端阅览
王金英, 张景林, 彭英健. 用于纳米微反应器的微乳液的相行为研究[J]. 中北大学学报（自然科学版）, 2009,30(4):349-353.

王金英, 张景林, 彭英健. Study on the Phase Behavior of Microemulsion System as a Nano-Reactor[J]. 2009, 30(4): 349-353.
王金英, 张景林, 彭英健. 用于纳米微反应器的微乳液的相行为研究[J]. 中北大学学报（自然科学版）, 2009,30(4):349-353. DOI：

王金英, 张景林, 彭英健. Study on the Phase Behavior of Microemulsion System as a Nano-Reactor[J]. 2009, 30(4): 349-353. DOI：

摘要

W/O型微乳液以其独特的结构可以用来制备纳米粒子的微反应器.为了遴选一个适用于制备纳米粒子的微乳液体系

利用相图分别研究了失水山梨醇单油酸酯(Span80)和聚氧乙烯(20)失水山梨醇单油酸酯(Tween80)混合表面活性剂、助表面活性剂、油相烷烃、温度等对W/O型微乳液的形成及微乳区面积的影响.研究结果证明:m(Span80)/m(Tween80)质量比为10/2

正己醇为助表面活性剂

且混合表面活性剂与正己醇的质量比为2/1

正辛烷为油相

温度为40℃

是一个适合用于纳米微反应器的W/O型微乳液体系.

Abstract

The water in oil microemulsion(W/O) is used as the nano-reactor for preparing nano-particles because of its unique structure.In order to screen a suitable microemulsion system for preparing nano-particles

the influencing factors including such as Span80

Tween80

co-surfactants

aliphatic hydrocarbons

temperature were researched by phase diagram.The testing results indicate that the suited W/O microemulsion should be formed as following:(1) the mass ratio of m(Span80)/m(Tween80) is 10/2;(2) n-hexyl alcohol as a perfect co-surfactant and the mass ratio of surfactant to co-surfactant is 2/1;(3) n-octane as oil-phase;(4) 40 ℃ as optimal temperature.

关键词

Keywords

references

罗敏,陈水林.W/O微乳液法制备纳米微粒的研究[J].山东化工,2003,32(4):27-29.Luo Min,Chen Shuilin.Preparation of nano-particles by W/O microemulsion process[J].Shandong ChemicalIndustry,2003,32(4):27-29.(in Chinese)

邵庆辉,古国榜,章莉娟.微乳反胶团体系在纳米超微颗粒制备中的应用[J].化工进展,2002,21(2):136-139.Shao Qinghui,Gu Guobang,Zhang Lijuan.Application development of microemulsion inverse-miceller system in thepreparation of nanometer ultermicro particles[J].Chemical Industry and Engineering Progress,2002,21(2):136-139.(in Chinese)

褚春莹,陈国华,范金石,等.季铵盐型阳离子甲壳低聚糖表面活性剂的相图和微乳液结构[J].高分子材料科学与工程,2003,19(5):154-156.Chu Chunying,Chen Guohua,Fan Jinshi,et al.Study on the phase diagram and microemulsion structure of quarternarycationics of chitosan[J].Polymer Materials Science and Engineering,2003,19(5):154-156.(in Chinese)

张朝平,邓伟.微乳液制备超细Ni-Fe复合物微粒[J].无机材料学报,2001,16(3):481.Zhang Chaoping,Deng Wei.Preparation of ultrafine Ni-Fe composite particles by microemulsion[J].Journal ofInorganic Materials,2001,16(3):481.(in Chinese)

Zhou Z H,Wang J,Liu X,et al.Synthesis of Fe3O4nanoparticles fromemulsions[J].J.Mater.Chem.,2001,11:1704-1709.

Lim G K,Wang J,Ng S C,et al.Formation of nanocrystalline hydroxyapatite in NP-5 and NP-9 surfactantmicroemulsions[J].Mater.Lett.,1996,28:431.

Can L M,Zhang L H.Synthesis of BaSO4nanoparticles from emulsions[J].Mater.Chem.Phys.,1995,40:94.

Chen C C,Chao C Y.Controled formation of nanoparticles from microemulsions[J].Chem.Mater.,2000,12:1516.

闫景辉,张鸣,连洪州,等.微乳液体系相图的研究及其在纳米氟化物制备中的应用[J].高等学校化学学报,2005,26(6):1006-1009.Yan Jinghui,Zhang Ming,Lian Hongzhou,et al.Phase diagrams of microemulsion systems and its application to thesynthesis of fluoride nanoparticles[J].Chemical Journal of Chinese Universities,2005,26(6):1006-1009.(inChinese)

崔正刚,殷福珊.微乳液化技术及应用[M].北京:中国轻工业出版社,2001:134-135.

滕弘霓,陈宗淇.醇对非离子表面活性剂所形成微乳液的影响[J].吉林化工学院学报,1996,13(4):8-12.Teng Hongni,Chen Zongqi.The effects of alcohol on the microemulsion composed of non-ionic surfactant[J].Jouranl of Jilin Institute of Chemical Technology,1996,13(4):8-12.(in Chinese)

Onori G,Santuci A.IR investingations of water structure in AOT reverse micellar aggregates[J].J.Phys.Chem.,1993,97(20):5430-5434.

Bansal V K,Shah D O,O'Connell J P.Influenece of alkyl chain length compatibility on microemulsion structureand solubilization[J].J.Collid.Interface Sci.,1980,75(2):462.

孙华,路福绥,赵辉.氰戊菊酯微乳液相行为及其结构转变[J].应用化学,2005,22(7):780-783.Sun Hua,Lu Fusui,Zhao Hui.Phase behavior and structural transitions in fenvalerate microemulsion[J].ChineseJournal of Applied Chemistry,2005,22(7):780-783.(in Chinese)

浏览量

371

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

孔雀绿-磷锑钼杂多酸光度法测定钢样中的磷

甲醇-柴油微乳燃料工艺研究

基于元学习与VAE⁃GAN的META⁃VAEGAN⁃DNN网络入侵检测方法

鱼类自主游动时摆频与摆幅的最优组合研究

面向量子信息的单光子探测的机制、器件及电路设计研究进展