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1. 北京航空航天大学交通科学与工程学院
2. 清华大学 汽车安全与节能国家重点实验室
纸质出版:2013
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李鹏程, 裴普成, 何勇灵, 等. 车用PEM燃料电池活化条件的优化[J]. 中北大学学报(自然科学版), 2013,34(2):178-182.
李鹏程, 裴普成, 何勇灵, et al. Optimization of the Activation Condition of a PEM Fuel Cell for Automotive[J]. 2013, 34(2): 178-182.
活化对车用质子交换膜燃料电池性能有重要影响.通过设计燃料电池变流强制活化程序
对实验室设计制造的燃料电池单片进行了4次活化实验.活化实验一、实验二和实验三的结果显示
经过活化燃料电池的性能得到了提升
但是提高幅度不大;而且燃料电池在加载至0.5A/cm2以上时
电压下降较快.对氧气不加湿进行了活化实验四
结果表明电池的最大加载电流密度由1.06A/cm2提高至1.75A/cm2
电池的性能得到了明显的提升.
The activation process has an important impact on the performance of a proton exchange membrane(PEM) fuel cell for automotive.A forced current-change activation procedure was designed and used to active homemade PEM fuel cell four times.The results of the first three activation show that the performance of the fuel cell is elevated
but the elevation is not quite big.Moreover
the voltage of the fuel cell decreased fast when the fuel cell was loaded at 0.5 A/cm2 and above.The forth activation was carried on with the oxygen not being humidified.The results demonstrate that the performance of the fuel cell is improved obviously and the maximum load current density is increased from 1.06 A/cm2 to 1.75 A/cm2.
Pathapati P R,Xue X,Tang J.A new dynamic modelfor predicting transient phenomena in a PEM fuel cellsystem[J].Renewable Energy,2005,30(1):1-22.
Panha K,Fowler M,Yuan Xiaozhi.Accelerateddurability testing via reactants relative humiditycycling on PEM fuel cells[J].Applied Energy,2012,93:90-97.
Placca L,Kouta R.Fault tree analysis for PEM fuelcell degradation process modeling[J].InternationalJournal of Hydrogen Energy,2011,36(19):12393.
Mayer T,Kreyenberg D,Wind J,et al.Feasibilitystudy of 2020 target costs for PEM fuel cells andlithium-ion batteries:A two-factor experience curveapproach[J].International Journal of HydrogenEnergy,2012,37(19):14463-14474.
Moein-Jahromi M.Performance prediction of PEMfuel cell cathode catalyst layer using agglomeratemodel[J].International Journal of Hydrogen Energy,2012,37(23):17954-17966.
Jia Ruiliang,Dong Siming,Hasegawa Takuya,et al.Contamination and moisture absorption effects on themechanical properties of catalyst coated membranes inPEM fuel cells[J].International Journal of HydrogenEnergy,2012,37(8):6790-6797.
O′rourke J,Ramani M,Arcak M.In situ detection ofanode flooding of a PEM fuel cell[J].InternationalJournal of Hydrogen Energy,2009,34(16):6765.
朱科,张继炎,单忠强,等.用EIS研究PEMFC膜电极的活化机理[J].电源技术,2006,30(1):41-43.Zhu Ke,Zhang Jiyan,Shan Zhongqiang,et al.Studyof activation mechanism of membrane electrodeassembly in PEMFC by EIS[J].Chinese Journal ofPower Sources,2006,30(1):41-43.(in Chinese)
朱科,陈延禧.质子交换膜燃料电池膜电极活化工艺及机理[J].电源技术,2002,26(4):267-268.Zhu Ke,Chen Yanxi.Technology and mechanism ofactivation for membrane electrode assembly in protonexchange membrane fuel cell[J].Chinese Journal ofPower Sources,2002,26(4):267-268.(in Chinese)
罗马吉.质子交换膜燃料电池电堆活化过程研究[J].武汉理工大学学报,2006,28(2):499-502.Luo Maji.Study on activation process of a PEM fuelstack[J].Journal of Wuhan University ofTechnology,2006,28(2):499-502.(in Chinese)
Qi Zhigang,Kaufman A.Enhancement of PEM fuelcell performance by steaming or boiling the electrode[J].Journal of Power Sources,2002,109(1):227.
He Chunzhi,Qi Zhigang.An electrochemical methodto improve the performance of air cathodes andmethanol anodes[J].Electrochem.Solid-StateLett.,2002,5(8):181-183.
Qi Zhigang.Activation of low temperature PEM fuelcells[J].Journal of Power Sources,2002,111(1):181-184.
Qi Zhigang.Quick and effective activation of proton-exchange membrane fuel cells[J].Journal of PowerSources,2002,114(1):21-31.
Xu Zhiqiang,Qi Zhigang,Kaufman A.Activation ofproton-exchange membrane fuel cells via COoxidative stripping[J].Journal of Power Sources,2006,156(2):281-283.
Xu Zhiqiang,Qi Zhigang,He Chunzhi.Combinedactivation methods for proton-exchange membranefuel cells[J].Journal of Power Sources,2006,156(2):315-320.
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